Method of making a multicolor light display by graded mesaing

ABSTRACT

There is disclosed a multicolor monolithic light display comprising a pair of matrices of light emitting diodes in an integral structure which pair of matrices are alternately or simultaneously scannable to produce a red, green or orange display. One matrix includes a plurality of gallium arsenide phosphide (GaAsXP1-X) red light emitting diodes while the other matrix includes gallium phosphide green light emitting diodes. The light emitting diodes are arranged in a geometric pattern of columns and rows with the first matrix interposed with the second matrix so that an alphanumeric character produced by one matrix will appear at almost the same physical location as a character of the alternate color. Row and column address lines are provided for each matrix so that a strobing format logic address system can affect lighting of the individual diodes for producing an alphanumeric character or graphic display in either one color or the other or if both matrices are addressed simultaneously in a combined color. There are also disclosed alternate methods of manufacturing the foregoing multicolor display.

United States Patent [:91

Russ

1 METHOD OF MAKING A MULTICOLOR LIGHT DISPLAY BY GRADED MESAING [75] Inventor: Malcolm 1. Russ, Scottsdale, Ariz.

{73] Assignee: Motorola, 1nc., Chicago, 111.

{22} Filed: Nov. 2, 1973 [21} Appl. No.: 414,070

Related U.S. Application Data [02] D vision of Ser. No. 230,293, Feb. 29, 1972,

abandoned.

[52] [1.8. CI. 148/175; 148/174; 148/178; 313/108 DX; 357/16; 357/17, 357/56 [51] int. Cl. H011 7/36 [58] Field of Search 148/175, 187, 186, 174,

148/178; 313/108 DX; 317/235 R, 235 AG; 315/169; 357/56, 16, 17

OTHER PUBLICATIONS Murray, L. et a1; Lighting up in a Group, in Electronics, March 1968 pp. 104-110 [TK 7800 E 58]. Finch, W. et a1; Preparation of Get/H P By vapor phase reaction, in J. Electrochem. Soc, July 1961 pp.

1 1 June 17, 1975 Dierscllke, E; Effect of Donor Concentration... from Gap Diodes; in .1. Appl. Phys, 11(1) 1970 pp. 321-328.

Primary ExaminerWalter R. Satterfield Attorney, Agent, or Firm-Vincent J. Rauner', Henry T. Olsen [57] ABSTRACT There is disclosed a multicolor monolithic light display comprising a pair of matrices of light emitting diodes in an integral structure which pair of matrices are alternately or simultaneously scannable to produce a red, green or orange display. One matrix includes a plurality of gallium arsenide phosphide (GaAs -P red light emitting diodes while the other matrix includes gallium phosphide green light emitting diodes. The light emitting diodes are arranged in a geometric pattern of columns and rows with the first matrix interposed with the second matrix so that an alphanumeric character produced by one matrix will appear at almost the same physical location as a character of the alternate color. Row and column address lines are provided for each matrix so that a strobing format logic address system can affect lighting of the individual diodes for producing an alphanumeric character or graphic display in either one color or the other or if both matrices are addressed simultaneously in a combined color. There are also disclosed alternate methods of manufacturing the foregoing multicolor display.

3 Claims, 4 Drawing Figures METHOD OF MAKING A MULTICOLOR LIGHT DISPLAY BY GRADED MESAING This is a division of application Scr. No. 230,293, filed Feb. 29. l972, and now abandoned.

BACKGROUND OF THE INVENTION This invention relates to alphanumeric displays and more particularly to a multicolor alphanumeric display. Still more particularly the invention is related to a multicolor monolithic light emitting diode display which is scannably addressable to produce characters in alternative or simultaneous colors.

As pointed out in the co-pending application of Michael G. Coleman and John A. Keil, Ser. No. l98,221 filed Nov. 12, 197i, and assigned to the present assignec, visual readout devices such as alphanumeric displays, are utilized for many purposes such as computer readouts, process control instrumentation, aircraft and automotive instrument panels and various other indicators such as clocks and gauges. In many of these uses it would be desirable if the display could operate in a differential color mode so as to provide an additional indicator of the meaning of the information. For example, a direct reading altimeter for an aircraft might be programmed so that altitudes below a certain height might appear in a distinctive color to further warn the pilot of the position of the aircraft. Also. since the multicolor basically can occupy the same panel space as a single color display two distinct types of information may be displayed in the same panel space by the use of one color to indicate one type of information and another color to indicate still another type of information. Thus. a multicolor display can occupy less space and provide additional functions not presently available from standard display devices.

The practical realization of the matrix display of this type requires precision photolithography as developed for semiconductor integrated circuits and silicon material by planar processing. While the aforementioned patent application results in a useful multicolor display, it does require the use of liquid epitaxy process to grow efficient red light emitting gallium phosphide (Zn-O) diodes. Liquid epitaxial processes do not readily produce a precision, flat epitaxial growth. Thus, it is preferred to utilize with the accordance of the invention an alternative material, gallium arsenide phosphide, for the red emitting diodes which material can be grown by a vapor epitaxial process. Further, in any matrix display which is directly addressable from logic and which has no intrinsic memory in the display itself the total dis play must be scanned faster than the eye responds.

Obviously if there are several thousand elements in the display then the time in which current flows through a given segment is short to obtain reasonable brightness and extremely high current level must be passed through the segment during the short address time. If this type of time sharing is to be successful in large displays it is essential that the light output be proportional to the current so that the pulse brightness during the short address time is usefully high. Red light emitting gallium phosphide (Zn()) suffers from the defeet that it saturates at modest current level. Thus, it is desirable again to use the gallium arsenide phosphide as the red emitting material because this material has a characteristic wherein the brightness is proportional to current up to very high current levels.

SUMMARY OF THE INVENTION It is a primary object of this invention to provide an improved multicolor display device wherein gallium arsenide phosphide is utilized for the red emitting diodes.

A further object of the invention is to provide a method of manufacturing the aforementioned monolithic light emitting diode display device.

In accordance with the aforementioned objects there is provided a multicolor light display comprising a first matrix of gallium phosphide light emitting diodes and a second matrix of gallium arsenide phosphide light emitting diodes each of said matrices being arranged in columns and rows in an epituxially graded monolithic structure.

THE DRAWINGS Further objects and advantages of the invention will be obvious to one skilled in the art from the following complete description thereof and from the drawings wherein:

FIG. 1 is a plan view of a multicolor monolithic light emitting diode display device in accordance with the preferred embodiment of the invention depicted herein somewhat schematically;

FIG. 2 is an isometric view of a portion of the device of FIG. 1 in partial cross section.

FIG. 3 is a. partial cross section depicting a monolithic structure in accordance with the embodiment of the invention and FIG. 4 is another partial cross section of another embodiment of the monolithic structure.

DETAILED DESCRIPTION In accordance with the preferred embodiment of the invention there is shown in FIG. I the multicolor light emitting diode array comprising a monolithic semiconductor support structure 20 containing a plurality of green light emitting diodes 21 and a second plurality of red light emitting diodes 22 in a pair of geometric matrices of rows and columns. The green light emitting diodes 21 are addressed by row address lines 23 and column address lines 24. A red light emitting diode 22 is addressed by row address lines 25 and column address lines 26. As shown, each matrix has a row of six diodes and a column containing eleven diodes making a total of sixtv-six light emitting diodes in each matrix. Through the address lines 23, 24, 25 and 26, a suitable strobing or scanning type logic can individually address any of the light emitting diodes to cause each to emit light in a suitable alphanumeric pattern in either or both colors. In the preferred embodiment of the invention the column lines 24 and 26 are connected to a single diffused conductive tunnei which simplifies the interconnection pattern. However, if desired the metalization may take a more conventional two-layer metalization pattern.

The display is shown in greater detail in FIG. 2 wherein the substrate 20 has thereon a plurality of mesas 27 of N type gallium phosphide. Diffusions 28 of zinc or cadmium doping material form PN junctions 29 in each of the mesas 27. A highly conductive channel or tunnel 30 underlies the mesa and connects with the column address line 24 to define the cathode contact. The conductive channel 30 is highly doped with either tellurium, sulphur or selenium. Anode contact for each of the green light emitting diodes 21 is obtained through metalization stripes 31 overlying the dielectric layer 32 which covers the substrate in mesas 27. The stripes 31 connect to the row address lines 23. The metalization stripes 31 make contact to the anodes through suitable windows as is well known.

The matrix of red light emitting diodes 22 is interspersed between the mesas 27 by the formation of diffusions 33 of zinc or cadmium doping to form PN junctions 34 in the surface region of the body of the substrate 20. The anodes of the light emitting diodes 22 are contacted by suitable metalization stripes 35 which form the row Contact connections to the row address line and the column address lines 26 can contact the cathodes of the diodes 22 through the conductive channel 30. Obviously if the resistivity of the channel is too high for proper addressing, a second layer of metalization can be formed on top of the substrate and mesas to form column connection stripes.

The graded material structure of the monolithic array in accordance with the preferred embodiment of the invention is depicted in FIG. 3 and is schematically represented showing a starting substrate 201 of gallium arsenide which may be doped to give it an N conductivity. By suitable vapor deposition techniques an epitaxial layer graded in composition from 100% gallium arsenide to a final composition of about 60% gallium arsenide (GaAs P is grown thereon from a source of gallium arsenic and phosphorus. During the vapor epitaxial process an increasing amount of phosphine gas is introduced in the process to grade the layer 202 until GaAs ,-,P is attained. Epitaxial deposition is then continued to form a coherent uniform layer 203 of GaAs P, preferably, N doped with tellurium, sulphur or selenium to form the N regions for the red light emitting diodes. The wafer is then removed from the epitaxial chamber and the diffusion forming the channels 30 may then be formed by suitable photolithographic techniques. A mask defining what will be the mesa regions 27 is then placed over the wafer and following which epitaxial grading from GaAs P continues to form the layer 204 which grades to gallium phosphide by eliminating arsenic from the vapor deposition sourcing material. A uniform iayer of gallium phosphide suit ably doped with tellurium, selenium. or sulphur is then deposited to form the N conductivity region of the green light emitting diodes. It will be apparent that the graded gallium arsenide phosphide layer 204 and galiiurn phosphide layer 205 may be made uniform across the entire wafer and the mesas formed by etching techniques thereafter.

An alternative process for graded growth of gallium phosphide and (iaAs ,;P structure necessary for producing the multicolor display is schematically depicted in FIG. 4 wherein the starting substrate 211 is gallium phosphide upon which a layer 212 of N doped gallium phosphide epitaxially produced. Following suitable masking a graded layer 213 of GaAs P is grown to form mesas and a coherent uniform layer 214 of GaAs P doped to provide suitable N conductivity is grown thereon to form suitable mesas. in accordance with the alternative embodiment it will be apparent that the red light emitting diodes 22 i! then be produced in the mesa regions while the green light emitting diodes 21 will be produced in the gallium phosphide layer 212 by suitable P diffusions.

While it has been assumed in the foregoing. that either gallium arsenide or gallium phosphide wafers have been utilized as the starting material it will be apparent to one skilled in the art that silicon or germanium wafers may be utilized and epitaxial layers of gallium arsenide or gallium phosphide deposited thereon followed by the aforementioned graded deposition and mesa growing steps to produce the necessary structure. It will also be noted that the GaAs P, may be GaAs P to emit yellow light. Within the above mentioned disclosure it will be appreciated that suitable further modifcations may be made therein without departing from the spirit and scope of the invention.

What is claimed is:

1. A process for the manufacture of a multi-color monolithic light display comprising:

providing a substrate of a semiconductor material of a first composition; epitaxially depositing thereon a semiconductor material layer graded from said first composition to a semiconductor material of a second composition; continuing the deposition of said second composition material to form a coherent layer on said graded layer;

masking selected portions of said layer of said second composition material; epitaxially depositing mesas of semiconductor material on the unmasked portions of said layer of the second composition material, which mesas are graded from the said second composition material to a semiconductor material of a third composition;

continuing deposition of said third composition material to form a coherent layer thereof on the surface of said mesas;

masking selected portions of said mesa and said layer of the second composition material; and

diffusing dopants into selected unmasked portions thereof to form PN junctions in the surface of said mesas and in the surface of the layer of the second composition material between said mesas.

2. A process as recited in claim 1 wherein the surface of said mesas is gallium phosphide and the surface of said substrate is GaAs P 3. A process as recited in claim 1 wherein the surface of said mesas is GaAs P and the surface of said substrate is 621?. 

1. A PROCESS FOR THE MANUFACTURE OF A MULTI-COLOR MONOLITHIC LIGHT DISPLAY COMPRISING: PROVIDING A SUBSTRATE OF A SEMICONDUCTOR MATERIAL OF A FIRST COMPOSITION, EPITAXIALLY DEPOSITING THEREON A SEMICONDUCTOR MATERIAL LAYER GRADED FROM SAID FIRST COMPOSITION TO A SEMIICONDUCTOR MATERIAL OF A SECOND COMPOSITION, CONTINUOUSLY THE DEPOSITION OF SAID SECOND COMPOSITION MATERIAL TO FORM A COHERENT LAYER ON SAID GRADED LAYER, MASKING SELECTED PORTIONS OF SAID LAYER OF SAID SECOND COMPOSITION MATERIAL, EPITAXIALLY DEPOSITING MESAS OF SEMICONDUCTOR MATERIAL ON THE UNMASKED PORTIONS OF SAID LAYER OF THE SECOND COMPOSITION MATERIAL, WHICH MESAS ARE GRADED FROM THE SAID SECOND COMPOSITION MATERIAL TO A SEMICONDUCTOR MATERIAL OF A THIRD COMPOSITION, CONTINUING DEPOSITION OF SAID THIRD COMPOSITION MATERIAL TO FORM A COHERENT LAYER THEREOF ON THE SURFACE OF SAID MESAS, MASKING SELECTED PORTIONS OF SAID MESA AND SAID LAYER OF THE SECOND COMPOSITION MATERIAL, AND DIFFUSING DOPANTS INTO SELECTED UNMASKED PORTIONS THEREOF TO FORM PPN JUNCTIONS IN THE SURFACE OF SAID MESAS AND IN THE SURFACE OF THE LAYER OF THE SECOND COMPOSITION MATERIAL BETWEEN SAID MESAS.
 2. A process as recited in claim 1 wherein the surface of said mesas is gallium phosphide and the surface of said substrate is GaAs.6P.4.
 3. A process as recited in claim 1 wherein the surface of said mesas is GaAs.6P.4 and the surface of said substrate is GaP. 